Transition-metal-free oxidative trifluoromethylation of unsymmetrical biaryls with trifluoromethanesulfinate.

نویسندگان

  • Yu-Dong Yang
  • Kanji Iwamoto
  • Etsuko Tokunaga
  • Norio Shibata
چکیده

A transition-metal-free direct oxidative trifluoromethylation of unsymmetrical biaryls has been achieved by the simple combination of trifluoromethanesulfinate and phenyliodine bis(trifluoroacetate). The trifluoromethylation is selectively observed in the electron-rich arenes.

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عنوان ژورنال:
  • Chemical communications

دوره 49 48  شماره 

صفحات  -

تاریخ انتشار 2013